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Arsenic Removal Studies Conducted by
Hungerford & Terry, Inc.
Hungerford & Terry, Inc. has
conducted numerous pilot studies within the United States demonstrating
the effectiveness of using filtration for arsenic removal, the most
recent of which include municipalities in Michigan, Nevada, California,
and Arizona.
The principal
of treatment is to co-precipitate the arsenic with iron and filter the
resulting floc. Many water sources have iron naturally
occurring in the water and require treatment before use. In such instances, the water can be treated for both iron
and arsenic using the same equipment. Applications that do not have
iron, or have insufficient iron to adequately reduce the arsenic, can
use ferric chloride to supplement the treatment process.
H&T has treated water
sources with various arsenic levels. The highest arsenic levels
have been encountered in the more arid regions of the United States,
i.e. Southwest United States. Regardless of the arsenic
concentration, it was readily treated by complexing the arsenic with
iron and directly filtering the constituents together. The arsenic
ranged from as low as 12 ppb to as high as over 80 ppb. The
arsenic was typically reduced to 3-4 ppb, often reaching non-detectable
levels.
The species state of
arsenic can impact the removal efficiency. Arsenite (As+3) must
first be converted to Arsenate (As+5) to best utilize this
technology. The conversion to As+5 is known to be
easily accomplished with chlorine. The conversion, if any,
represents a minimal chlorine demand given the fact that arsenic
concentrations are low compared to any iron that is typically present.
Additionally, the amount of chlorine required for maintaining a
disinfected system is magnitudes of order greater than the typical
arsenic concentration.
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